Unique data is stored in the primary key and unique key fields. The primary key field never accepts NULL value but a unique key field accepts a NULL value.
Example: Create below table
CREATE TABLE shopping.myusers(
uid int(10) PRIMARY KEY,
uname VARCHAR(50) UNIQUE KEY,
password VARCHAR(50));
Now insert NULL in unique key, you won't get any error
INSERT INTO shopping.myusers(uid, uname, password) VALUES(1, NULL, '1234');
Query OK, 1 row affected (0.01 sec)
Now insert NULL in primary key, you will get error:
mysql> INSERT INTO shopping.myusers(uid, uname, password) VALUES(NULL, NULL, '1234');
ERROR 1048 (23000): Column 'uid' cannot be null